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Biochar and Bio-oil

Image via Wikipedia The growing concerns about climate change have brought biochar, a charcoal produced from biomass combustion, into limelight. Biochar is a carbon-rich, fine-grained residue which can be produced either by ancient techniques (such as covering burning biomass with soil and allowing it to smoulder ) or state-of-the-art modern pyrolysis processes. Combustion and decomposition of woody biomass and agricultural residues results in the emission of a large amount of carbon dioxide. Biochar can store this CO 2 in the soil leading to reduction in GHGs emission and enhancement of soil fertility. Biochar holds the promise to tackle chronic human development issues like hunger and food insecurity, low agricultural productivity and soil depletion, deforestation and biodiversity loss, energy poverty, air pollution and climate change. Thus, biochar could make a difference in the energy-starved countries of Asia, Africa and Latin America as well as the industrialized world wi...

Biofuels - An Introduction

The term ‘Biofuel’ refers to liquid or gaseous fuels for the transport sector that are predominantly produced from biomass. A variety of fuels can be produced from biomass resources including liquid fuels, such as ethanol, methanol, biodiesel, Fischer-Tropsch diesel, and gaseous fuels, such as hydrogen and methane. The biomass resource base for biofuel production is composed of a wide variety of forestry and agricultural resources, industrial processing residues, and municipal solid and urban wood residues. The agricultural resources include grains used for biofuels production, animal manures and residues, and crop residues derived primarily from corn and small grains (e.g., wheat straw). A variety of regionally significant crops, such as cotton, sugarcane, rice, and fruit and nut orchards can also be a source of crop residues. The forest resources include residues produced during the harvesting of forest products, fuelwood extracted from forestlands, residues gene...

Biomass Pyrolysis

Pyrolysis is the thermal decomposition of biomass occurring in the absence of oxygen. It  is the fundamental chemical reaction that is the precursor of both the combustion and gasification processes and  occurs naturally in the first two seconds.  The products of biomass pyrolysis include biochar, bio-oil and gases including methane, hydrogen, carbon monoxide, and carbon dioxide.   Depending on the thermal environment and the final temperature, pyrolysis will yield mainly biochar at low temperatures, less than 450  0 C, when the heating rate is quite slow, and mainly gases at high temperatures, greater than 800   0 C, with rapid heating rates. At an intermediate temperature and under relatively high heating rates, the main product is bio-oil. Pyrolysis can be performed at relatively small scale and at remote locations which enhance energy density of the biomass resource and reduce transport and handling costs.    Heat transfer is a critical area in pyrolysis as the pyrolysis process is...

BioOil - The Future Oil

Bio-oil is a dark brown liquid and has a similar composition to biomass. It has a much higher density than woody materials which reduces storage and transport costs. Bio-oil is not suitable for direct use in standard internal combustion engines. Alternatively, the oil can be upgraded to either a special engine fuel or through gasification processes to a syngas and then bio-diesel. Bio-oil is particularly attractive for co-firing because it can be more readily handled and burned than solid fuel and is cheaper to transport and store.   Co-firing of bio-oil has been demonstrated in 350 MW gas fired power station in Holland, when 1% of the boiler output was successfully replaced. It is in such applications that bio-oil can offer major advantages over solid biomass and gasification due to the ease of handling, storage and combustion in an existing power station when special start-up procedures are not necessary. In addition, bio-oil is also a vital source for a wide range of organic co...

Biochar Sequestration

Biochar sequestration is considered carbon negative as it results in a net decrease in atmospheric carbon dioxide over centuries or millennia time scales. Instead of allowing the organic matter to decompose and emit CO2, pyrolysis can be used to sequester the carbon and remove circulating CO2 from the atmosphere and stores it in virtually permanent soil carbon pools, making it a carbon-negative process. According to Johannes Lehmann of Cornell University, biochar sequestration could make a big difference in the fossil fuel emissions worldwide and act as a major player in the global carbon market with its robust, clean and simple production technology.  The use of pyrolysis also provides an opportunity for the processing of agricultural residues, wood wastes and municipal solid waste into useful clean energy. Although some organic matter is necessary for agricultural soil to maintain its productivity, much of the agricultural waste can be turned directly into biochar, bio-oil, and synga...